MATERIAL SAFETY DATA SHEETS MANUFACTURER: XENTEX®CHEMICAL INDUSTRIES INC. P.O.B. 220 STREETSVILLE -------------- MISSISSAUGA, ONTARIO XENTEX®1995 CANADA L5M 2B8 -------------- MSDS NUMBER: 0026 DATE OF MSDS: NOVEMBER 4,1996 FOR EMERGENCY CONTACT - Tel: 905-826-2999 Fax: 905-826-8272 ------------------------------------------------------------------------------------ SECTION 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------------ PRODUCT NAME: XENTEX®1995 CHEMICAL DESCRIPTION: MIXTURE FORMULA: NA SYNONYMS: NA MANUFACTURER: XENTEX®CHEMICAL INDUSTRIES INC. ------------------------------------------------------------------------------------ SECTION 2 - HAZARDOUS INGREDIENTS ------------------------------------------------------------------------------------ CHEMICAL IDENTITY CAS NUMBER % Weight OSHA / PEL ACGIH / TLV 1. NA NA NA NA NA 2. ETHANOL 64-17-5 10 - 30 1000 PPM 1000 PPM 3. NA NA NA NA NA 4. NA NA NA NA NA 5. NA NA NA NA NA ----------------------------------------------------------------------------------- SECTION 3 - PHYSICAL DATA ------------------------------------------------------------------------------------ PHYSICAL STATE: CLEAR LIQUID SPECIFIC GRAVITY ( 25 C / 25 C ) : 0.90 VAPOR DENSITY : NA VAPOR PRESSURE ( mm Hg ): NA BOILING POINT : NA FREEZING POINT: NA EVAPORATION RATE : NA % VOLATILE BY VOLUME : 100 SOLUBILITY IN WATER : MISCIBLE pH : 6 - 8 ------------------------------------------------------------------------------------ SECTION 4 - FIRE AND EXPLOSION HAZARD ------------------------------------------------------------------------------------ FLASH POINT ( CLOSED CUP ): 39 C FLAMMABLE LIMITS IN AIR ( LFL/UFL) : NA EXTINGUISHING MEDIA : USE SUFFICIENT VOLUME OF WATER, ALCOHOL FOAM, DRY CHEMICAL, AND CO2 TO EXTINGUISH FIRE SPECIAL FIRE FIGHTING PROCEDURE : FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIP- MENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. REMOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE AND EXPLOSION HAZARDS : VAPOURS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CON- TAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. AUTOIGNITION TEMPERATURE : NA SENSITIVITY TO STATIC DISCHARGE: NON IDENTIFIED SENSITIVITY TO MECHANICAL IMPACT: NONE IDENTIFIED TOXIC COMBUSTION GASES: OXIDES OF CARBON, AND FORMALDEHYDE. ------------------------------------------------------------------------------------ SECTION 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------------ THRESHOLD LIMIT VALUE ( TLV / TWA ): N/E STEL / PEL : N/E ORAL RAT LD 50 ( mg / Kg ) : > 10300 ( WHMIS ) CARCINOGENICITY : NONE IDENTIFIED NTP: NO IARC: NO Z LIST: NO OSHA REG: NO TERATOGENICITY / MUTAGENICITY/ SYNERGISTIC / SENSITIZATION: MAY OCCUR DUE TO ETHANOL REPRODUCTIVE TOXICITY: NONE IDENTIFIED PRIMARY ROUTES OF ENTRY : EYE CONTACT, SKIN CONTACT, INHALATION OF MIST OR VAPOUR, INGESTION, AND ABSORPTION. EFFECTS OF OVEREXPOSURE INHALATION OF MIST OR VAPOUR: IS HARMFUL, IRRITATION OF MUCOUS MEMBRANES, COUGH, NAUSEA,HEADACHE, DIZZINESS, VOMITING, NARCOSIS, RESPIRATORY FAILURE, CENTRAL NERVOUS SYSTEM DEPRESSION, AND POSSIBLE LOW BLOOD PRESSURE. INGESTION : IS HARMFUL AND MAYBE FATAL, NAUSEA, HEADACHE, DIZZINESS, VOMITING, VOMITING MAY CAUSE FURTHER PULMONARY INJURY, POSSIBLE BLINDNESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, AND HEARING LOSS. SKIN CONTACT : IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS. EYE CONTACT : IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE. SKIN ABSORPTION : MAY OCCUR. TARGET ORGANS :EYES,SKIN, CENTRAL NERVOUS SYSTEM,RESPIRATORY SYSTEM,AND GI TRACT. OTHER HEALTH HAZARDS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: EYE,SKIN,LIVER/KIDNEY DISORDERS EMERGENCY AND FIRST AID PROCEDURES INGESTION: IF CONSCIOUS,GIVE LARGE AMOUNT OF WATER AND INDUCE VOMITING.KEEP AT REST. CALL A PHYSICIAN. INHALATION : REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. KEEP WARM AND QUIET. GET MEDICAL ATTENTION. EYE CONTACT : IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTACT LENSES IF EASILY POSSIBLE. IF IRRITATION PERSISTS GET MEDICAL ATTENTION. SKIN CONTACT : WASH SKIN WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. ------------------------------------------------------------------------------------ SECTION 6 - REACTIVITY DATA ------------------------------------------------------------------------------------ STABILITY : STABLE HYDROLYSIS : NA CONDITIONS TO AVOID : HEAT, FLAME, AND OTHER SOURCES OF IGNITION. HAZARDOUS POLYMERIZATION : WILL NOT OCCUR DECOMPOSITION PRODUCTS : OXIDES OF CARBON, AND FORMALDEHYDE. INCOMPATIBLES : STRONG OXIDIZING AGENTS, STRONG ACIDS, ALUMINUM, MAGNESIUM, ZINC, HALOGENS, ALDEHYDES, AMINES, AND AMMONIA. ------------------------------------------------------------------------------------ SECTION 7- SPILL AND DISPOSAL PROCEDURE ------------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE LAND SPILL: WEAR SUITABLE PROTECTIVE GEARS. SHUT OFF ALL IGNITION SOURCES. PREVENT ADDITIONAL DISCHARGE OF MATERIAL. CONTAIN SPILL. FOR SMALL SPILLS COLLECT SPILLS INTO A CLEAN WASTE CONTAINER. ABSORB THE REMAINING PRODUCT WITH EARTH OR SAND AND DISPOSE ACCORDING TO LOCAL LAWS. WASH ANY REMAINING SLIPPERY SURFACES WITH WATER. FOR LARGE SPILLS PROVIDE DIKING FOR CONTAINMENT, IMPLEMENT CLEANUP PROCEDURES, AND IF IN PUBLIC AREA KEEP PUBLIC AWAY AND ADVISE AUTHORITIES. PREVENT LIQUID FROM ENTERING SEWER, WATERCOURSES, OR LOW AREAS. WATER SPILL:. INFORM ENVIRONMENTAL AUTHORITIES. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. ----------------------------------------------------------------------------------- SECTION 8 - INDUSTRIAL PROTECTIVE EQUIPMENT ----------------------------------------------------------------------------------- VENTILATION: USE ADEQUATE GENERAL OR LOCAL VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTIONS IS REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS 1000 PPM. AT CONCENTRATIONS ABOVE 1000 PPM A SELF- CONTAINED BREATHING APPARATUS IS ADVISED. EYE / SKIN PROTECTION : SAFETY GLASSES WITH SIDE SHIELDS, LONG SLEEVES, AND RUBBER GLOVES. OTHERS : EYE WASH FOUNTAIN AND SHOWER IN THE AREA OF WORK IS RECOMMENDED. ------------------------------------------------------------------------------------ SECTION 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------------ STORAGE : STORE IN TIGHTLY CLOSED CONTAINER IN COOL , DRY, AND VENTILATED PLACE FOR STORAGE OF FLAMMABLE LIQUIDS. DO NOT STORE IN VICINITY OF INCOMPATIBLE MATERIALS. HANDLING : BOND AND GROUND CONTAINER WHEN TRANSFERRING LIQUIDS. AVOID PRODUCING CHEMICAL MIST. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. ------------------------------------------------------------------------------------ SECTION 10 - REGULATORY INFORMATION ------------------------------------------------------------------------------------ WHMIS: B3 (COMBUSTIBLE LIQUID ), D2A ( OTHER TOXIC EFFECTS ) SARA / TITLE III HAZARD CATEGORIES AND LISTS: ACUTE (YES) , CHRONIC (YES), FLAM- MABILITY (YES), PRESSURE (NO), REACTIVITY (NO), EXTREMELY HAZARDOUS SUBSTANCE (NO), CERCLA HAZARDOUS SUBSTANCE (YES), SARA 313 TOXIC CHEMICALS (NO), TSCA INVENTORY (YES). TDG / D.O.T./ I.M.O./ I.C.A.O. : FLAMMABLE LIQUID, N.O.S. ( ETHANOL ), CLASS 3.3, UN 1993, PACKING GROUP III. DSL / NDSL / TSCA: THE (ALL) CONSTITUENT(S) OF THIS PRODUCT IS (ARE) INCLUDED ON THE DSL / NDSL OF CEPA AND TSCA INVENTORY. CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS NONE OF THE SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY. MICHIGAN CRITICAL MATERIALS REGISTER: THIS PRODUCT DOES NOT CONTAIN ANY INGREDIENT LISTED ON THE MICHIGAN CRITICAL MATERIALS REGISTER. ------------------------------------------------------------------------------------ SECTION 11 - PRECAUTIONARY WARNING ------------------------------------------------------------------------------------ XENTEX SAFETY DATA SYSTEM: HEALTH 2 MODERATE FLAMMABILITY 2 MODERATE REACTIVITY 1 LOW CONTACT 1 LOW NFPA 704: HEALTH-0, FLAMMABILITY-2 REACTIVITY-0 NPCA-HMIS: HEALTH-0, FLAMMABILITY-2, REACTIVITY-0 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe ----------------------------------------------------------------------------------- SECTION 12 - ABBREVIATIONS ----------------------------------------------------------------------------------- NA = NOT AVAILABLE OR NOT APPLICABLE N/E = NOT ESTABLISHED ----------------------------------------------------------------------------------- SECTION 13 - OTHER INFORMATION ----------------------------------------------------------------------------------- THE INFORMATION, DATA, AND REFERENCES CONTAINED HEREIN ARE BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL- INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE AND IS NOT PACKAGE SIZE SPECIFIC, NOR SHOULD IT BE TAKEN AS A WARRANTY OR REPRESENTATION. THIS INFORMATION IS OFFERED SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFI- CATION. ANY USE OF THE INFORMATION MUST BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL,STATE,AND LOCAL LAWS AND REGULATIONS. NOTHING HEREIN IS TO BE CONSTRUED AS RECOMMENDING ANY PRACTICE IN VIOLATION OF ANY PATENT OR IN VIOLATION OF ANY LAW OR REGULATION. IT IS THE USER'S RESPONSIBILITY TO DETERMINE FOR HERSELF / HIMSELF THE SUITABILITY OF THIS PRODUCT FOR A SPECIFIC PURPOSE AND TO ADOPT SUCH SAFETY PRECAUTION AS MAY BE NECESSARY. WE MAKE NO WARRANTY AS TO THE RESULTS TO BE OBTAINED IN USING ANY OF OUR PRODUCTS.SINCE ALL CONSEQUENCES OF USING AND HANDLING THIS PRODUCT ARE NOT KNOWN TO US, AND CONDITIONS OF USE AND HANDLING ARE NOT UNDER OUR CONTROL, WE MUST NECESSARILY DISCLAIM ALL LIABILITY WITH RESPECT TO THE USE, APPLICATION, STORAGE, AND TRANSPORTATION OF THIS PRODUCT. XENTEX® SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THIS PRODUCT. SEE THE PRODUCT BULLETIN, PRODUCT LABEL, THE REVERSE SIDE OF INVOICE OR PACKING SLIP, AND THE CUSTOMER AGREEMENT FOR ADDITIONAL TERMS AND CONDITIONS OF SALE. ------------------------------------------------------------------------------------- XENTEX® IS A REGISTERED TRADEMARK OF XENTEX CHEMICAL INDUSTRIES INC.